Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
DHW Demand
Place a link between the Common and Calling connections of the cylinder thermostat
Ensure the link is safe and secure then refit the thermostats cover
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Once the link is in place the cylinder thermostat is bypassed and
the hot water should now fire regardless of the cylinder temperature.
Measure the voltage on the Brown wire to the Hot Water zone valve.
1: Is mains voltage present?
2: If voltage is now present on the brown wire, does the valve move to the open position?
Once test is completed remove the link.
Note: The colour and position of the wires will vary between systems and components.