Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
DHW Demand
CH Demand
Locate the Orange wires in the wiring centre
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure voltage to earth on the Orange wire(s).
The Orange wire takes the voltage from the valves end switch to supply the power to run the pump and boiler.
Is mains voltage present on the Orange wire(s)?
Note: The colour and position of the wires will vary between systems and components.