Set Appliance State:

Set Multimeter to Resistance Set meter to measure resistance
CH Demand
Isolate Mains Power to appliance as per TOPs P4
Disconnect the Main PCB Connector PL8 from the PCB

Measurement:

Measure the resistance across the Red wire (connection 4 marked R out) and the Black wire (connection 5 marked R in) on the Main Terminal Block.
Note:
If no Room Thermostat is fitted, there should be a link wire (1) connected between connections R out and R in on the Main Terminal Block.