Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
Selector Switch to Hot Water and Heating
Gain access to PCB (use insulation mat as necessary)
Ensure NO CH demand
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Test for mains voltage between the black wire (top) on connector X9 and earth.