Set Appliance State:

Mains Power Off
Set Multimeter to AC Voltage Set meter to measure AC Volts
CH/HW switch in HW position
Ensure that the boiler is cold and ready for Pre-heat
Boiler On/Off switch ON
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure mains voltage across gas valve 2
(main gas valve solenoid) white (Live) wire
and blue (Neutral) wire.