Set Appliance State:

Mains Power Off
Gas Off
Set Multimeter to DC Volts Set meter to measure DC Volts
CH switch OFF
Ensure secondary heat exchanger is cool and requires pre-heat (this can be achieved by running the DHW with the gas to the appliance turned off)
Gas On
Mains Power On

Measurement:

Pre-heat switch ON.
Allow fan to run and main burner to ignite.
Measure voltage across the connections on the modulating solenoid (grey wires).