Set Appliance State:

Mains Power Off
Gas Off
Set Multimeter to AC Volts Set meter to measure AC Volts
Ensure secondary heat exchanger is cool and requires pre-heat (this can be achieved by running the DHW with the gas to the appliance turned off)
CH switch OFF
Gas On
Mains Power On

Measurement:

Pre-heat switch ON.
Allow fan to run.
Measure voltage across connections D12 marked N (red wire) and D14 marked GV1 (red wire) on the 7 pin connector, central of the three connectors towards the top of main PCB 23.