Set Appliance State:

Mains Power Off
Gas Off
Set Multimeter to DC Volts Set meter to measure DC Volts
Turn Hot Water Tap On
DHW temperature set to maximum position
Flow rate at tap set to approx 7 ltr/min
Gas On
Mains Power On

Measurement:

Allow boiler to run and heat DHW.
Measure voltage at the terminals of the modulating solenoid.
Does the voltage measured reduce as the temperature of the DHW increases?