Set Appliance State:

Mains Power Off
Set Multimeter to DC Volts Set meter to measure DC Volts
Turn Hot Water Tap On
Use Insulation Mat as required
Selector switch to hot water
DHW temperature selector to maximum
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the voltage across the blue (-ve probe) and white wires (+ve probe) on J6 (black connector) on main pcb. 0 V DC should be measured.
Turn hot water tap Off.
Repeat test. 5 V DC should be measured.
Note:
For this test it is easiest to use the front of the connector where exposed silver connections can be seen to make the best connection.