Set Appliance State:

Mains Power Off
Set Multimeter to AC Volts Set meter to measure AC Volts
Selector switch to hot water
DHW Temperature selector to maximum
Gas On
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Ensure the boiler is not in lockout. Take the following measurements when sparking commences.
Measure the voltage across the brown and blue wires at the 5 pin connector on the gas valve.
Measure the voltage across the black and blue wires at the 5 pin connector on the gas valve.
Mains voltage expected.
Note:
The boiler will go to lockout if it does not ignite and will need resetting.