Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
CH Demand
Attach temperature probe to the flow directly underneath the overheat thermostat coil
CH temperature set to MAX
Selector Switch in Heating & Hot Water Position
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Observation:

Allow boiler to ignite and establish for CH. Run boiler up to temperature, does the burner shut down at approximately 82°C or does overheat occur?
Notes:
To reduce time taken for this test you may wish to turn off some radiators.