Set Appliance State:

On/Off Switch OFF
Set Multimeter to DC Volts Set meter to measure DC Volts
Turn Hot Water Tap On
Isolate Mains Power to appliance as per TOPs P4
CH temperature switch to minimum
DHW temperature switch to maximum
Gain access to PCB (use insulation mat as necessary)
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Turn On/Off switch to On.
Measure the voltage across connection 5 (green wire) and connection 4 (white wire) on connector X4 on the PCB.
Approximately 2.4 volts DC should be present.
Is the voltage as expected?