Set Appliance State:

Mains Power Off
On/Off Switch OFF
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
External controls calling for heat
CH temperature switch to maximum
DHW temperature switch to minimum
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Turn On/Off switch to On.
Allow fan to run.
Measure the voltage across connection 10 (brown wire) on connector X6 and connection 2 (blue wire) on connector X1 on the PCB.
Mains voltage expected.
Note:
Some voltage will be present before the fan runs, take the reading once the fan is running as described above.