Set Appliance State:

Mains Power Off
Set Multimeter to DC Volts Set meter to measure DC Volts
CH Demand
Selector Switch in CH/DHW Winter position
Heating Thermostat set to Maximum
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the DC Voltage across one of the Thermostat connections marked A1 or P1 (Violet wires) and the B4 connection (Grey wire) on the Connector B multi-plug on the PCB.
Repeat this measurement using the other Thermostat connection marked A1 or P1 (Violet wire).