Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to DC Volts Set meter to measure DC Volts
DHW Demand
Gas On
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow fan to start.
Measure between the green connection on the gas valve solenoid and the neutral at the incoming mains terminal strip.
Expect approximately 24vdc.
Note:
Voltage will only be present for approximately 1-3 seconds during the sparking stage of ignition phase the appliance will try to ignite several times before going to lockout.
Click Here for Guidance on Resetting the Appliance