Set Appliance State:

Set Multimeter to mVolts DC Set meter to measure DC mVolts
Turn Hot Water Tap On
Isolate Mains Power to appliance as per TOPs P4
Remove the main control box cover to expose the control PCB
Disconnect flame sense electrode lead from connection marked 'FLAME TCI' on the control board
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Reset lockout as necessary.
Allow fan to run and burner to ignite.
Measure millivolts DC voltage across the end of the flame sense lead and a suitable earth point.
Does the multimeter show a DC millivoltage greater than 100 when burner is alight?
Note:
Burner will only be alight for approximately 3 seconds as it will not prove.