Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to DC Volts Set meter to measure DC Volts
Gain access to PCB (use Insulation Mat as required)
ON/OFF switch in the ON position
Gas On
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

DHW temp selector at approx 35°C.
Turn hot water tap ON.
Measure voltage at PCB connector X2, between pins 6 and 8 (red wires).
Does the voltage reduce as the boiler reaches temperature?