Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
Selector Switch to Hot Water and Heating
No Demands for CH
Gain access to PCB (use insulation mat as necessary)
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the AC voltage at the black wire on the incoming mains terminal strip that leads to the PCB connector X3 and the incoming neutral.
Note:
On some appliances the incoming terminal strip is located differently and has been rotated through 180° from the one shown.