Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Gain access to PCB (use Insulation Mat as required)
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Reset boiler if required.
Allow fan to run and ignition sequence to commence.
Measure the voltage at connector CN1 connection 7 (red wire) on the ignition PCB and a suitable neutral.
Once the burner has lit voltage should increase from approximately 0V AC to mains voltage.