Set Appliance State:

Set Multimeter to AC Volts Set meter to measure AC Volts
Isolate Mains Power to appliance as per TOPs P4
CH temperature selector to 0 position
DHW temperature selector to 0 position
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow appliance to self check and return to standby mode.
Measure voltage between the inline connector of the flame sense lead and the main earth point on the appliance.
Expected voltage approximately 27 volts AC.