Set Appliance State:

Mains Power Off
Set Multimeter to DC Volts Set meter to measure DC Volts
Turn Hot Water Tap On
CH temperature selector to 0 position
DHW temperature selector to 0 position
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Reset lockout as necessary.
DHW temperature selector to maximum position.
Allow fan to run and burner to ignite.
Measure voltage across the connections on gas valve 3 (black leads, solenoid farthest to the left).
Expected voltage approximately 20 volts DC.