Set Appliance State:

Mains Power Off
Set Multimeter to AC Volts Set meter to measure AC Volts
Turn Hot Water Tap On
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Reset appliance as necessary
Allow burner to ignite and establish
Measure the AC voltage between the Brown and bottom Blue connector at the gas valve as boiler operates. Mains voltage will be present.
Turn Hot Water Tap OFF
(using DHW isolation valve if necessary)
Does the voltage remain after demand ends?