Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Disconnect plug from Flue Sensor

Measurement:

Measure resistance across the 2 exposed pins.
This is the temperature of the condensed flue products so is unlikely to go above 60-70 °C unless there's a problem.
The resistance will vary according to the boiler temperature but should conform to the table below:
Temperature °CResistance in kOhms
20 - 3012.0 to 8.5
30 - 408.5 to 6.0
40 - 506.0 to 4.2
50 - 604.2 to 3.0
60 - 703.0 to 2.2
70 - 802.2 to 1.7