Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to DC Volts Set meter to measure DC Volts
Turn Hot Water Tap On
Gain access to PCB (use Insulation Mat as required)
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Reset appliance as necessary.
Once the appliance begins the sparking stage of its ignition sequence, measure the voltage between pins 6 and 7 (brown and blue wires) on X6b connector at the PCB.
Approximately 210V DC expected.
Note:
If a white board is fitted connector is in same location but is called X6 instead of X6b.