Set Appliance State:

Mains Power Off
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Selector switch to heating and hot water position
CH temperature selector to maximum
DHW temperature selector to minimum
Clock in timed mode in an on period
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure voltage across terminal 3 on external control terminal block marked room thermostat, and the neutral connection on the main terminal block marked N on the PCB.