Set Appliance State:

Gas Off
Set Multimeter to mVolts DC Set meter to measure DC mVolts
Isolate Mains Power to appliance as per TOPs P4
Selector Switch in HW position.
Connect crocodile clip to outer sheath of Thermocouple.
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

With Pilot lit depress the Gas Valve Control Knob.
Measure the voltage across the Thermocouple and Interrupt connection on the Main Gas Valve.