Set Appliance State:

Gas Off
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Isolate Mains Power to appliance as per TOPs P4
Selector Switch in CH & HW position
Gain access to PCB as necessary
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

With a Central Heating Demand, measure Mains Voltage across Relay 1 connection 4 or 8 (Grey) and N (Blue) on the Appliance Terminal Block.