Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
Turn Hot Water Tap On
Gain access to PCB (use Insulation Mat as required)
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Reset boiler as necessary and allow the appliance to complete its self check.
During the sparking stage of the ignition sequence, measure the voltage between pin 8 (blue) and pin 9 (orange) on connector HV2 at the PCB, voltage will be present for approximately 5 seconds.
The boiler will attempt to light 5 times before going to lockout, with approximately 35 seconds between each attempt.
Mains voltage expected.