Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Gain access to PCB (use Insulation Mat as required)
Disconnect plug marked "EMS" on left hand side of boiler wiring and make safe
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Observation:

Reset boiler.
Does the fault code reoccur or does the boiler now enter standby?