Set Appliance State:

Mains Power Off
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Selector Switch to Hot Water and Heating
CH thermostat to MAX
Gas On
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the AC voltage at the black wire on the incoming mains terminal strip that leads to the PCB connector X3 and the incoming neutral.
Expect mains voltage 240vAC
Note:
On some appliances the incoming terminal strip is located differently and has been rotated through 180° from the one shown.