Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
Function selector in 0 position
All CH controls calling
Gain access to PCB (use insulation mat as necessary)
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Switch selector to the CH/DHW position, measure the voltage across the black lead (neutral) and red lead (live) in the middle of connector X3 on the PCB.
Expect Mains voltage (230 VAC).
Switch the selector back to HW position.
Run DHW tap
Measure voltage across the black lead (neutral) and white lead (live) in the middle of connector X3 on the PCB.
Expect Mains voltage (230 VAC).