Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Selector Switch to Hot Water and Heating
CH thermostat to MAX
Gain access to PCB (use insulation mat as necessary)
Gas On
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure for AC voltage between the black wire at the mains terminal strip that runs from the selector switch to the neutral at the incoming mains.
Expect mains voltage 240vAC.
Note:
On some appliances the incoming terminal strip is located differently and has been rotated through 180° from the one shown.