Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
Turn Hot Water Tap On
Gain access to PCB (use Insulation Mat as required)
Disconnect the flame sense lead from the ignition PCB
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the voltage between the disconnected spade at the ignition PCB and a suitable earth point.
Once the fan runs is approximately 200V AC now present?