Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Remove the plastic cover from the hot water
microswitch and disconnect wires

Measurement:

With no demand for DHW measure the resistance across the hot water microswitch terminals.
Resistance should be open circuit.
Note:
Pulling the microswitch out of its housing may make this
test easier if the boiler is not in a convenient location.