Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Disconnect orange wires from overheat thermostat

Measurement:

Measure resistance across spade terminals of overheat thermostat.
Note:
Overheat thermostat is of the auto reset type and should only be open
circuit if boiler is at excessive temperature i.e. above 110 degrees C.