Set Appliance State:

Mains Power Off
Set Multimeter to DC Volts Set meter to measure DC Volts
Turn Hot Water Tap On
Boiler ON/OFF Switch OFF
CH Temperature Selector OFF
DHW Temperature Selector to Max
Ensure DHW is cool
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Boiler ON/OFF Switch ON.
Allow Fan to run and Burner to ignite for at least 4 seconds.
Measure Voltage across the connections of the Modulating Solenoid (blue wires).