Set Appliance State:

Mains Power Off
Set Multimeter to DC Volts Set meter to measure DC Volts
CH Demand
Boiler ON/OFF Switch OFF
CH Temperature Selector to Max
DHW Temperature Selector OFF
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Boiler ON/OFF Switch ON.
Measure Voltage across the connections of the Modulating Solenoid (blue wires).