Set Appliance State:

Gas On; Pilot On
Set Multimeter to mVolts DC Set meter to measure DC mVolts
Isolate Mains Power to appliance as per TOPs P4
Ensure Boiler is cool

Measurement:

Ignite pilot by depressing the gas control knob and pressing the ignition button.
Keeping the gas control knob depressed, check the
voltage on each of the high limit thermostat terminals.
Both readings should be 8 millivolts or above.