Set Appliance State:

Gas Off
Set Multimeter to AC Voltage Set meter to measure AC Volts
Turn Hot Water Tap On
Isolate Mains Power to appliance as per TOPs P4
Selector switch to HOT WATER position
Gain access to PCB (use insulation mat as necessary)
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Depress the gas control knob. Allow the boiler to execute its purge delay period and measure the voltage across connection 55 (blue wire) and connection 56 brown wire at connector D on the PCB.
Note:
Gas control knob should be fully depressed while measurement is being taken.