Set Appliance State:

Mains Power Off
Set Multimeter to mVolts DC Set meter to measure DC mVolts
Turn Hot Water Tap On
Gas On
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Depress the gas control knob.
Allow the boiler to execute its purge period and the pilot to ignite.
Keep the gas control knob depressed, and measure the millivoltage between the thermocouple interrupter and a suitable earth point.