Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Remove the connector plug marked X1 from the PCB

Measurement:

Test 1: Measure the resistance across the Brown wire (potentiometer wiper terminal, middle terminal) and the Blue wire at the CH Potentiometer(Boiler Thermostat). With the potentiometer turned fully down (anti-clockwise) the resistance should be short circuit (or very near short circuit).
Increase the potentiometer (clockwise) and observe the resistance increasing to a maximum of approximately 10 Kohms.
Test 2: Measure the resistance across the Brown wire (potentiometer wiper terminal, middle terminal) and the Black wire. The resistance should now be approximately short circuit (stat at Maximum).
Turn down the potentiometer fully (anti-clockwise) and the resistance should increase to approximately 10 K ohms.