Set Appliance State:

Mains Power Off
Set Multimeter to AC Volts Set meter to measure AC Volts
Turn Hot Water Tap On
Boiler On/Off switch Off
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Boiler On/Off switch On.
Reset lockout if necessary.
Allow fan to run and ignition sequence to commence.
Measure the AC voltage between the flame sense electrode lead at the flame sense electrode and a suitable earth point.
Observe multi-meter, voltage should read
approximately 55 volts AC.
As burner ignites voltage should reduce to
approximately 35 volts AC.