Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Temperature Set meter to measure Temperature
Turn Hot Water Tap On
Attach temperature probe to the hot water output pipe of the boiler
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Run the hot tap for a time sufficient to allow the boiler to heat the water and reach a stable temperature.
Measure the temperature of the hot water
pipe as it leaves the boiler.
Compare this to the temperature of the water
at the hot tap.