Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
Turn Hot Water Tap On
Use Insulation Mat as required
Gain access to PCB
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow the boiler to enter its ignition sequence, measure the voltage between pins 3 (blue) and 4 (brown) on connector X14.
Mains voltage should be present for approx. 5 seconds (as the boiler reaches sparking stage of its ignition sequence), then return to 0V. This will happen 5 times before the boiler locks out.