Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Remove the burner assembly from the boiler

Measurement:

Inspect the flame detection electrode for general condition.
Make sure the gap to the burner is 7.5mm (+/- 1mm)
Check for continuity (zero resistance) between the ends of the flame detection electrode.