Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
Turn Hot Water Tap On
Use Insulation Mat as required
Gain access to the PCB
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow the boiler to enter its ignition sequence.
During the sparking phase of the sequence, measure the voltage across pins 5 (green) and 6 (black) of the X14 connector on the PCB.
Expect mains voltage.