Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Disconnect connector from X22 on the PCB

Measurement:

Measure resistance across the two red leads at the disconnected connector, and the approximate temperature at the sensors location.
The resistance will vary according the boiler temperature but should conform approximately to the table below at the appropriate temperature to ensure it is within range and in calibration
Temperature °CResistance in kOhms
2010
30 6.6
405.8
503.1
602
701.5
801.1