Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Disconnect the rectification lead from the condensate trap at the inline connector
Remove the 6 pin connector from the PCB
Disconnect the rectification lead from the sensing electrode (make sure it does not touch the boiler case or components - wrap in insulation tape if necessary)

Measurement:

Test 1:
Measure the resistance between the inline connector removed from the condensate trap and pin 1 (white wire) on the 6 pin connector.
Expect continuity / zero resistance.
Test 2:
Measure resistance between the spade connector removed from the condensate trap and a suitable earth.
Expected open circuit / O.L.
Are the resistances measured as expected?