Set Appliance State:

Mains Power Off
Set Multimeter to AC Voltage Set meter to measure AC Volts
Turn Hot Water Tap On
Gas On
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow fan to run and ignition sequence to commence and burner to ignite and establish.
Measure the voltage across black and white wires at the gas valve.
Expect voltage of approximately 35v AC or greater.
Is the voltage measured as expected?