Set Appliance State:

Mains Power Off
Set Multimeter to DC Volts Set meter to measure DC Volts
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the DC voltage between the left hand terminal of the 24v external controls thermostat and the earth point on the boiler chassis.
Expect approximately 24 Vdc.